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The Chemistry of Essential Oils

The chemistry of essential oils is complex, but in general, they consist of many hundreds of molecular compounds with atoms of hydrogen, carbon and oxygen. These can be subdivided into three principal groups :

Hydrocarbons

The hydrocarbons consist mainly of :

Oxygenated Compounds

The oxygenated compounds consist mainly of :

Miscellaneous

These can be grouped as :

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Terpenes

Examples

limonene, pinene, camphene, cadinene, caryophyllene, cedrene, dipentine, phellandrene, terpinene, sabinene, myrcene

{short description of image}This is the molecular structure of d-limonene, or 4-isopropenyl-1-methylcyclohexene

{short description of image}This is the molecular structure of pinene.

Aromatherapy Properties

anti-septic, anti-viral

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Sesquiterpines

Examples

chamazulene, farnesol

Aromatherapy Properties

anti-bacterial, anti-inflammatory

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Esters

These are found in almost all essential oils and have very useful properties.

Examples

linalyl acetate, geranyl acetate, bornyl acetate, eugenyl acetate, lavendulyl acetate

Aromatherapy Properties

fungicidal, sedative, fruity aroma

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Aldehydes

These are found in the lemon-scented oils such as melissa, lemongrass, lemon verbena, lemon eucalyptus and citronella.

Examples

citral, citronellal, neural, benzaldehyde, cinnamic aldehyde, cuminic aldehyde, perillaldehyde

{short description of image}This is the molecular structure of benzaldehyde.

Aromatherapy Properties

anti-septic, sedative

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Ketones

Many ketones are toxic and are found in plants such as mugwort, tansy, sage and worm-wood. Non-toxic ketones include jasmone ( in jasmine ) and fenchone ( in fennel ).

Examples

thujone, pulegone, jasmone, fenchone, camphor, carvone, methone, methyl nonyl ketone, pinocamphone

{short description of image}This is a picture of thujone.

{short description of image}This is a picture of camphor.

Aromatherapy Properties

respiratory complaints - helps ease congestion and clears mucus

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Alcohols

Generally non-toxic and useful in producing uplifting oils. Linalol is found in lavender and citronellol is found in rose and geranium.

Examples :

linalol, citronellol, geraniol, borneol, methol, nerol, terpineol, farnesol, vetiverol, benzyl alcohol, cedrol

{short description of image}This is a picture of citronellol

{short description of image}This is the molecular structure of geraniol.

Aromatherapy Properties

anti-septic, anti-viral, uplifting oils

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Phenols

Often strongly stimulating but can be skin irritants. Found in clove, bay, thyme, oregano and savory.

Examples

eugenol, thymol, carvacrol, methyl eugenol, methyl chavicol, anethole, safrole, myristicin, apiol

{short description of image}This is the molecular structure of eugenol.

Aromatherapy Properties

anti-bacterial, stimulating

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Oxides

Cineol is the principal constituent of eucalyptus oil and is by far the most important oxide in essential oils. It is found in other camphoraceous oils such as rosemary, bay, laurel, tea tree and cajeput.

Examples

cineol ( eucalyptol ), linalol oxide, ascaridol, bisabolol oxide, bisabolone oxide

Aromatherapy Properties

expectorant


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